Browsing by Subject "Dynamic Effects"
Now showing items 1-4 of 4
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(2011-02-22)The mechanism of three important aldol reactions and a biomimetic transamination is investigated using a combination of experimental kinetic isotope effects (KIEs), standard theoretical calculations and dynamics ...
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(2017-12-18)Statistical and nonstatistical rate theories help organic chemists understand reactions. The most widely used statistical rate model is transition state theory (TST). TST is an extremely useful model for describing organic ...
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(2011-10-21)The [2,3]-sigmatropic rearrangement is a pericyclic reaction of great synthetic utility to organic chemists. Within the scope of this reaction exist some cases in which the product corresponding to a [1,2] rearrangement ...
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(2017-06-26)Statistical models, like Transition State Theory (TST), are used in order to predict rates and selectivities of reactions. However, these models often fail to explain experimental results. In such cases, consideration of ...